Tris(1,10-phenanthroline)cobalt(II) bis(perrhenate) monohydrate
Identifieur interne : 000561 ( Main/Exploration ); précédent : 000560; suivant : 000562Tris(1,10-phenanthroline)cobalt(II) bis(perrhenate) monohydrate
Auteurs : Samah Toumi Akriche [Tunisie] ; Zeid Abdellah Al Othman [Arabie saoudite] ; Mohamed Rzaigui [Tunisie] ; Refaat Mohamed Mahfouz [Arabie saoudite]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2010.
Abstract
In the title compound, [Co(C12H8N2)3][ReO4]2·H2O, the CoII atom is coordinated by three 1,10-phenanthroline ligands in a distorted octahedral arrangement. In the crystal, the components are linked by O—H⋯O, C—H⋯O and aromatic π–π stacking [shortest centroid–centroid separation = 3.659 (5) Å] interactions.
Url:
DOI: 10.1107/S1600536810022750
PubMed: 21587733
PubMed Central: 3006859
Affiliations:
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Le document en format XML
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<front><div type="abstract" xml:lang="en"><p>In the title compound, [Co(C<sub>12</sub>
H<sub>8</sub>
N<sub>2</sub>
)<sub>3</sub>
][ReO<sub>4</sub>
]<sub>2</sub>
·H<sub>2</sub>
O, the Co<sup>II</sup>
atom is coordinated by three 1,10-phenanthroline ligands in a distorted octahedral arrangement. In the crystal, the components are linked by O—H⋯O, C—H⋯O and aromatic π–π stacking [shortest centroid–centroid separation = 3.659 (5) Å] interactions.</p>
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